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Electronic configuration of Zirconium (Zr)

Zirconium, atomic number 40: [Kr] 4d² 5s²

2, 8, 18, 10, 2Electrons per shell
2Unpaired electrons
d-blockGroup 4, period 5
91.224Atomic mass (u)

Full configuration

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d² 5s²

In the short form, [Kr] stands for the 36 electrons of krypton, the noble gas before zirconium. Only the electrons after it are written out.

Orbital diagram

Outer subshells only. Each box is an orbital; electrons fill singly first (Hund's rule), then pair up with opposite spins.

What the configuration tells you

Zirconium is in group 4, period 5, in the d-block. It has 2 unpaired electrons in the ground state, so the atom is paramagnetic.

Configuration of zirconium ions

IonConfigurationUnpairedMoment (BM)
Zr⁴⁺[Kr]00.00

Moment is the spin-only magnetic moment μ = √(n(n + 2)) Bohr magnetons, where n is the number of unpaired electrons. Positive ions lose electrons from the outermost shell first, so transition metals lose their 4s or 5s electrons before d.

Nearby elements

ZElementConfiguration
37Rubidium[Kr] 5s¹
38Strontium[Kr] 5s²
39Yttrium[Kr] 4d¹ 5s²
41Niobium[Kr] 4d⁴ 5s¹
42Molybdenum[Kr] 4d⁵ 5s¹
43Technetium[Kr] 4d⁵ 5s²

← YttriumNiobium →

Questions students ask

What is the electronic configuration of zirconium?

[Kr] 4d² 5s², or in full, 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d² 5s². Zirconium has atomic number 40.

How many electrons are in each shell of zirconium?

2, 8, 18, 10, 2 (K, L, M, N… shells in order).

How many unpaired electrons does zirconium have?

2 in the ground state, so zirconium atoms are paramagnetic.

What is the electronic configuration of Zr⁴⁺?

[Kr], with 0 unpaired electrons.

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