Rankwise

Electronic configuration of Molybdenum (Mo)

Molybdenum, atomic number 42: [Kr] 4d⁵ 5s¹

2, 8, 18, 13, 1Electrons per shell
6Unpaired electrons
d-blockGroup 6, period 5
95.95Atomic mass (u)

Full configuration

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d⁵ 5s¹

In the short form, [Kr] stands for the 36 electrons of krypton, the noble gas before molybdenum. Only the electrons after it are written out.

Orbital diagram

Outer subshells only. Each box is an orbital; electrons fill singly first (Hund's rule), then pair up with opposite spins.

Why it's an exception

Molybdenum, like chromium above it, takes a half-filled 4d⁵ 5s¹ instead of 4d⁴ 5s².

Configuration of molybdenum ions

IonConfigurationUnpairedMoment (BM)
Mo⁶⁺[Kr]00.00

Moment is the spin-only magnetic moment μ = √(n(n + 2)) Bohr magnetons, where n is the number of unpaired electrons. Positive ions lose electrons from the outermost shell first, so transition metals lose their 4s or 5s electrons before d.

Nearby elements

ZElementConfiguration
39Yttrium[Kr] 4d¹ 5s²
40Zirconium[Kr] 4d² 5s²
41Niobium[Kr] 4d⁴ 5s¹
43Technetium[Kr] 4d⁵ 5s²
44Ruthenium[Kr] 4d⁷ 5s¹
45Rhodium[Kr] 4d⁸ 5s¹

← NiobiumTechnetium →

Questions students ask

What is the electronic configuration of molybdenum?

[Kr] 4d⁵ 5s¹, or in full, 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d⁵ 5s¹. Molybdenum has atomic number 42.

How many electrons are in each shell of molybdenum?

2, 8, 18, 13, 1 (K, L, M, N… shells in order).

How many unpaired electrons does molybdenum have?

6 in the ground state, so molybdenum atoms are paramagnetic.

What is the electronic configuration of Mo⁶⁺?

[Kr], with 0 unpaired electrons.

Why is molybdenum an exception?

Molybdenum, like chromium above it, takes a half-filled 4d⁵ 5s¹ instead of 4d⁴ 5s².

Use these next