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Oxidation number of P in H3PO4

The oxidation number of phosphorus in H3PO4 is +5.

Step by step

  1. Known values: H = +1 (hydrogen is +1 with non-metals); O = −2 (oxygen is −2 in most compounds).
  2. Let the oxidation number of P be x. The sum over all atoms equals the overall charge, 0 for a neutral compound.
  3. 3(+1) + 4(−2) + x = 0
  4. −5 + x = 0, so x = +5
  5. x = +5

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Common oxidation numbers

Questions students ask

What is the oxidation number of P in H₃PO₄?

+5.

How do you find the oxidation number of phosphorus in H₃PO₄?

Known values: H = +1 (hydrogen is +1 with non-metals); O = −2 (oxygen is −2 in most compounds). Let the oxidation number of P be x. The sum over all atoms equals the overall charge, 0 for a neutral compound. 3(+1) + 4(−2) + x = 0 −5 + x = 0, so x = +5 x = +5

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