Rankwise

Electronic configuration of Sulphur (S)

Sulphur, atomic number 16: [Ne] 3s² 3p⁴

2, 8, 6Electrons per shell
2Unpaired electrons
p-blockGroup 16, period 3
32.06Atomic mass (u)

Full configuration

1s² 2s² 2p⁶ 3s² 3p⁴

In the short form, [Ne] stands for the 10 electrons of neon, the noble gas before sulphur. Only the electrons after it are written out.

Orbital diagram

Outer subshells only. Each box is an orbital; electrons fill singly first (Hund's rule), then pair up with opposite spins.

What the configuration tells you

Sulphur is in group 16, period 3, in the p-block. It has 2 unpaired electrons in the ground state, so the atom is paramagnetic.

Configuration of sulphur ions

IonConfigurationUnpairedMoment (BM)
S²⁻[Ar]00.00

Moment is the spin-only magnetic moment μ = √(n(n + 2)) Bohr magnetons, where n is the number of unpaired electrons.

Nearby elements

ZElementConfiguration
13Aluminium[Ne] 3s² 3p¹
14Silicon[Ne] 3s² 3p²
15Phosphorus[Ne] 3s² 3p³
17Chlorine[Ne] 3s² 3p⁵
18Argon[Ne] 3s² 3p⁶
19Potassium[Ar] 4s¹

← PhosphorusChlorine →

Questions students ask

What is the electronic configuration of sulphur?

[Ne] 3s² 3p⁴, or in full, 1s² 2s² 2p⁶ 3s² 3p⁴. Sulphur has atomic number 16.

How many electrons are in each shell of sulphur?

2, 8, 6 (K, L, M, N… shells in order).

How many unpaired electrons does sulphur have?

2 in the ground state, so sulphur atoms are paramagnetic.

What is the electronic configuration of S²⁻?

[Ar], with 0 unpaired electrons.

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