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Electronic configuration of Cobalt (Co)

Cobalt, atomic number 27: [Ar] 3d⁷ 4s²

2, 8, 15, 2Electrons per shell
3Unpaired electrons
d-blockGroup 9, period 4
58.933Atomic mass (u)

Full configuration

1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁷ 4s²

In the short form, [Ar] stands for the 18 electrons of argon, the noble gas before cobalt. Only the electrons after it are written out.

Orbital diagram

Outer subshells only. Each box is an orbital; electrons fill singly first (Hund's rule), then pair up with opposite spins.

What the configuration tells you

Cobalt is in group 9, period 4, in the d-block. It has 3 unpaired electrons in the ground state, so the atom is paramagnetic.

Configuration of cobalt ions

IonConfigurationUnpairedMoment (BM)
Co²⁺[Ar] 3d⁷33.87
Co³⁺[Ar] 3d⁶44.90

Moment is the spin-only magnetic moment μ = √(n(n + 2)) Bohr magnetons, where n is the number of unpaired electrons. Positive ions lose electrons from the outermost shell first, so transition metals lose their 4s or 5s electrons before d.

Nearby elements

ZElementConfiguration
24Chromium[Ar] 3d⁵ 4s¹
25Manganese[Ar] 3d⁵ 4s²
26Iron[Ar] 3d⁶ 4s²
28Nickel[Ar] 3d⁸ 4s²
29Copper[Ar] 3d¹⁰ 4s¹
30Zinc[Ar] 3d¹⁰ 4s²

← IronNickel →

Questions students ask

What is the electronic configuration of cobalt?

[Ar] 3d⁷ 4s², or in full, 1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁷ 4s². Cobalt has atomic number 27.

How many electrons are in each shell of cobalt?

2, 8, 15, 2 (K, L, M, N… shells in order).

How many unpaired electrons does cobalt have?

3 in the ground state, so cobalt atoms are paramagnetic.

What is the electronic configuration of Co²⁺?

[Ar] 3d⁷, with 3 unpaired electrons.

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